Hydroxo-Bridged Dicopper(II,III) and -(III,III) Complexes: Models for Putative Intermediates in Oxidation Catalysis

[Image: see text] A macrocyclic ligand (L(4–)) comprising two pyridine(dicarboxamide) donors was used to target reactive copper species relevant to proposed intermediates in catalytic hydrocarbon oxidations by particulate methane monooxygenase and heterogeneous zeolite systems. Treatment of LH(4) wi...

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Detalhes bibliográficos
Main Authors: Halvagar, Mohammad Reza, Solntsev, Pavlo V., Lim, Hyeongtaek, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Cramer, Christopher J., Tolman, William B.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4046753/
https://ncbi.nlm.nih.gov/pubmed/24821432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja503629r
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