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Copper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes

Enamines and enamides are useful synthetic intermediates and common components of bioactive compounds. A new protocol for their direct synthesis by a net alkene C–H amination and allylic amination by using catalytic Cu(II) in the presence of MnO(2) is reported. Reactions between N-aryl sulfonamides...

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Hlavní autoři: Liwosz, Timothy W., Chemler, Sherry R.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4038966/
https://ncbi.nlm.nih.gov/pubmed/23878099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201301800
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