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Rapidly reversible redox transformation in nanophase manganese oxides at room temperature triggered by changes in hydration

Chemisorption of water onto anhydrous nanophase manganese oxide surfaces promotes rapidly reversible redox phase changes as confirmed by calorimetry, X-ray diffraction, and titration for manganese average oxidation state. Surface reduction of bixbyite (Mn(2)O(3)) to hausmannite (Mn(3)O(4)) occurs in...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Birkner, Nancy, Navrotsky, Alexandra
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2014
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4035946/
https://ncbi.nlm.nih.gov/pubmed/24733903
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1320014111
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