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Rapidly reversible redox transformation in nanophase manganese oxides at room temperature triggered by changes in hydration
Chemisorption of water onto anhydrous nanophase manganese oxide surfaces promotes rapidly reversible redox phase changes as confirmed by calorimetry, X-ray diffraction, and titration for manganese average oxidation state. Surface reduction of bixbyite (Mn(2)O(3)) to hausmannite (Mn(3)O(4)) occurs in...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4035946/ https://ncbi.nlm.nih.gov/pubmed/24733903 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1320014111 |
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