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Rapidly reversible redox transformation in nanophase manganese oxides at room temperature triggered by changes in hydration
Chemisorption of water onto anhydrous nanophase manganese oxide surfaces promotes rapidly reversible redox phase changes as confirmed by calorimetry, X-ray diffraction, and titration for manganese average oxidation state. Surface reduction of bixbyite (Mn(2)O(3)) to hausmannite (Mn(3)O(4)) occurs in...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4035946/ https://ncbi.nlm.nih.gov/pubmed/24733903 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1320014111 |
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