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Boron Carboxylate Catalysis of Homoallylboration
[Image: see text] Boron tris(trifluoroacetate) is identified as the first effective catalyst for the homoallyl- and homocrotylboration of aldehydes by cyclopropylcarbinylboronates. NMR spectroscopic studies and theoretical calculations of key intermediates and transition states both suggest that a l...
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| Autori principali: | , , , |
|---|---|
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical
Society
2014
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4033657/ https://ncbi.nlm.nih.gov/pubmed/24754566 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500599h |
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