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Monooxo Molybdenum(VI) Complexes Possessing Olefinic Dithiolene Ligands: Probing Mo-S Covalency Contributions to Electron Transfer in DMSO Reductase Family Molybdoenzymes

A monooxo Mo(VI) model complex for the oxidized active site in the DMSOR family of molybdoenzymes has been synthesized and structurally characterized. The compound was obtained from the desoxo Mo(IV) derivative by clean oxygen atom transfer from an amine N–oxide in a manner similar to that observed...

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Dettagli Bibliografici
Autori principali: Sugimoto, Hideki, Tatemoto, Susumu, Suyama, Koichiro, Miyake, Hiroyuki, Mtei, Regina P., Itoh, Shinobu, Kirk, Martin L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4020915/
https://ncbi.nlm.nih.gov/pubmed/20491454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic100825x
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