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An energetic scale for equilibrium H/D fractionation factors illuminates hydrogen bond free energies in proteins
Equilibrium H/D fractionation factors have been extensively employed to qualitatively assess hydrogen bond strengths in protein structure, enzyme active sites, and DNA. It remains unclear how fractionation factors correlate with hydrogen bond free energies, however. Here we develop an empirical rela...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Wiley-Blackwell
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4005708/ https://ncbi.nlm.nih.gov/pubmed/24501090 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/pro.2435 |
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