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An energetic scale for equilibrium H/D fractionation factors illuminates hydrogen bond free energies in proteins

Equilibrium H/D fractionation factors have been extensively employed to qualitatively assess hydrogen bond strengths in protein structure, enzyme active sites, and DNA. It remains unclear how fractionation factors correlate with hydrogen bond free energies, however. Here we develop an empirical rela...

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Hlavní autoři: Cao, Zheng, Bowie, James U
Médium: Artigo
Jazyk:Inglês
Vydáno: Wiley-Blackwell 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4005708/
https://ncbi.nlm.nih.gov/pubmed/24501090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/pro.2435
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