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Cu-Free 1,3-Dipolar Cycloaddition Click Reactions To Form Isoxazole Linkers in Chelating Ligands for fac-[M(I)(CO)(3)](+) Centers (M = Re, (99m)Tc)

[Image: see text] Isoxazole ring formation was examined as a potential Cu-free alternative click reaction to Cu(I)-catalyzed alkyne/azide cycloaddition. The isoxazole reaction was explored at macroscopic and radiotracer concentrations with the fac-[M(I)(CO)(3)](+) (M = Re, (99m)Tc) core for use as a...

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Detalhes bibliográficos
Main Authors: Bottorff, Shalina C., Kasten, Benjamin B., Stojakovic, Jelena, Moore, Adam L., MacGillivray, Leonard R., Benny, Paul D.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3993946/
https://ncbi.nlm.nih.gov/pubmed/24483834
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic402825t
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