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Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents
[Image: see text] A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.
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| Main Authors: | , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2014
|
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3985922/ https://ncbi.nlm.nih.gov/pubmed/24621247 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja501560x |
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