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Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents

[Image: see text] A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.

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Bibliografiske detaljer
Main Authors: Zhu, Ye, Buchwald, Stephen L.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2014
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985922/
https://ncbi.nlm.nih.gov/pubmed/24621247
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja501560x
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