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Validity conditions for stochastic chemical kinetics in diffusion-limited systems

The chemical master equation (CME) and the mathematically equivalent stochastic simulation algorithm (SSA) assume that the reactant molecules in a chemically reacting system are “dilute” and “well-mixed” throughout the containing volume. Here we clarify what those two conditions mean, and we show wh...

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Bibliografske podrobnosti
Main Authors: Gillespie, Daniel T., Petzold, Linda R., Seitaridou, Effrosyni
Format: Artigo
Jezik:Inglês
Izdano: AIP Publishing LLC 2014
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3977787/
https://ncbi.nlm.nih.gov/pubmed/24511926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4863990
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