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The Deterministic Limit of Stochastic Chemical Kinetics
An analysis is presented of the approximating assumptions that underlie a recently proposed derivation of the traditional deterministic reaction rate equation from a discrete-stochastic formulation of chemical kinetics. It is shown that if the system is close enough to the thermodynamic limit, in wh...
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| Autor principal: | |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2651820/ https://ncbi.nlm.nih.gov/pubmed/19159264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp806431b |
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