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Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes
Catalytic, enantioselective, directed cross-aldol reactions of aldehydes are described. The addition of isobutyraldehyde trichlorosilyl enolate 2 to various aldehydes in the presence of 10 mol % bisphosphoramide 4 provides aldol products in high yields with moderate to good enantioselectivities. The...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
National Academy of Sciences
2004
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC397401/ https://ncbi.nlm.nih.gov/pubmed/15067133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307212101 |
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