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OH–Pd(0) interaction as a stabilizing factor in palladium-catalyzed allylic alkylations
In palladium-catalyzed alkylations of allylic acetates with malonate as nucleophile, catalysts with oxazoline ligands bearing hydroxymethyl substituents in 4-position have been shown by density functional theory computations to undergo a conformational change on nucleophilic attack, which is accompa...
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| Autori principali: | , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2004
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC397393/ https://ncbi.nlm.nih.gov/pubmed/15067129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307084101 |
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