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OH–Pd(0) interaction as a stabilizing factor in palladium-catalyzed allylic alkylations
In palladium-catalyzed alkylations of allylic acetates with malonate as nucleophile, catalysts with oxazoline ligands bearing hydroxymethyl substituents in 4-position have been shown by density functional theory computations to undergo a conformational change on nucleophilic attack, which is accompa...
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| Publicado en: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC397393/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15067129/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307084101 |
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