Mechanistic studies of the molybdenum-catalyzed asymmetric alkylation reaction

Enantiomerically enriched, deuterated branched carbonates (Z)-(S)-PhCH(OCO(2)Me)-CH = CHD (1-D), (Z)-(R)-PhCH(OCO(2)Me)CH = CHD (2-D), and linear carbonate (E)-(S)-PhCH = CHCHD(OCO(2)Me) (3-D) were used as probes in the Mo-catalyzed asymmetric allylic alkylation with sodium dimethyl malonate, cataly...

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Detalhes bibliográficos
Main Authors: Hughes, David L., Lloyd-Jones, Guy C., Krska, Shane W., Gouriou, Laure, Bonnet, Veronique D., Jack, Kevin, Sun, Yongkui, Mathre, David J., Reamer, Robert A.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
Assuntos:
Asymmetric Catalysis Special Feature Part I
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC397389/
https://ncbi.nlm.nih.gov/pubmed/15056759
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0306918101
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