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Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides

[Image: see text] The [2,3]- and [1,2]-sigmatropic rearrangements of ammonium ylides are studied by a combination of experimental, standard computational, and dynamic trajectory methods. The mixture of concerted [2,3] rearrangement and bond cleavage observed experimentally is accounted for by the ou...

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Detalles Bibliográficos
Main Authors: Biswas, Bibaswan, Collins, Sean C., Singleton, Daniel A.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2014
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3971961/
https://ncbi.nlm.nih.gov/pubmed/24579740
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4128289
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