Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation

Essentially complete atropdiastereoselectivity was realized in the preparation of biaryl diphosphine dioxide by asymmetric intramolecular Ullmann coupling and oxidative coupling with central-to-axial chirality transfer. A bridged C(2)-symmetric biphenyl phosphine ligand possessing additional chiral...

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Autori principali: Qiu, Liqin, Wu, Jing, Chan, Shusun, Au-Yeung, Terry T.-L., Ji, Jian-Xin, Guo, Rongwei, Pai, Cheng-Chao, Zhou, Zhongyuan, Li, Xingshu, Fan, Qing-Hua, Chan, Albert S. C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2004
Soggetti:
Asymmetric Catalysis Special Feature Part II
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC395991/
https://ncbi.nlm.nih.gov/pubmed/15067137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307774101
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