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Chiral biphenyl diphosphines for asymmetric catalysis: Stereoelectronic design and industrial perspectives
Two original chiral diphosphines, SYNPHOS and DIFLUORPHOS, have been synthesized on multigram scales. Their steric and electronic profiles have been established in comparison with the commonly used 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl and 6,6′-dimethoxy-2,2′-bis(diphenylphosphino)-1,1′-biphen...
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| Autori principali: | , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2004
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC395988/ https://ncbi.nlm.nih.gov/pubmed/15031423 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307620101 |
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