Chiral biphenyl diphosphines for asymmetric catalysis: Stereoelectronic design and industrial perspectives

Two original chiral diphosphines, SYNPHOS and DIFLUORPHOS, have been synthesized on multigram scales. Their steric and electronic profiles have been established in comparison with the commonly used 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl and 6,6′-dimethoxy-2,2′-bis(diphenylphosphino)-1,1′-biphen...

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Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Jeulin, Séverine, de Paule, Sébastien Duprat, Ratovelomanana-Vidal, Virginie, Genêt, Jean-Pierre, Champion, Nicolas, Dellis, Philippe
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: National Academy of Sciences 2004
Gaiak:
Asymmetric Catalysis Special Feature Part II
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC395988/
https://ncbi.nlm.nih.gov/pubmed/15031423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307620101
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