Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation

Essentially complete atropdiastereoselectivity was realized in the preparation of biaryl diphosphine dioxide by asymmetric intramolecular Ullmann coupling and oxidative coupling with central-to-axial chirality transfer. A bridged C(2)-symmetric biphenyl phosphine ligand possessing additional chiral...

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Bibliografiske detaljer
Main Authors: Qiu, Liqin, Wu, Jing, Chan, Shusun, Au-Yeung, Terry T.-L., Ji, Jian-Xin, Guo, Rongwei, Pai, Cheng-Chao, Zhou, Zhongyuan, Li, Xingshu, Fan, Qing-Hua, Chan, Albert S. C.
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2004
Fag:
Asymmetric Catalysis Special Feature Part II
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC395991/
https://ncbi.nlm.nih.gov/pubmed/15067137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307774101
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