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Synthesis of β-Hydroxy-α-haloesters through Super Silyl Ester Directed SYN-Selective Aldol Reaction

[Image: see text] Super silyl haloesters including chloro- and bromoacetate were synthesized and utilized for aldol reactions to give SYN-β-hydroxy-α-haloacetates in good yields with high diastereoselectivities. β-Hydroxy-α-fluoroacetate was obtained by lithiation of super silyl bromofluoroacetate....

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Oda, Susumu, Yamamoto, Hisashi
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2013
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3946542/
https://ncbi.nlm.nih.gov/pubmed/24205937
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402928p
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