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Synthesis of β-Hydroxy-α-haloesters through Super Silyl Ester Directed SYN-Selective Aldol Reaction
[Image: see text] Super silyl haloesters including chloro- and bromoacetate were synthesized and utilized for aldol reactions to give SYN-β-hydroxy-α-haloacetates in good yields with high diastereoselectivities. β-Hydroxy-α-fluoroacetate was obtained by lithiation of super silyl bromofluoroacetate....
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3946542/ https://ncbi.nlm.nih.gov/pubmed/24205937 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402928p |
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