Diastereoselective Additive Trifluoromethylation/Halogenation of Isoxazole Triflones: Synthesis of All-Carbon-Functionalized Trifluoromethyl Isoxazoline Triflones

Highly functionalized 5-trifluoromethyl-2-isoxazoline derivatives featuring a triflyl (SO(2)CF(3)) group at the 4-position were successfully synthesized via diastereoselective trifluoromethylation and halogenation of isoxazole triflones using the Ruppert– Prakash reagent. The trifluoromethylation is...

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Bibliografiska uppgifter
Huvudupphovsmän: Kawai, Hiroyuki, Sugita, Yutaka, Tokunaga, Etsuko, Sato, Hiroyasu, Shiro, Motoo, Shibata, Norio
Materialtyp: Artigo
Språk:Inglês
Publicerad: WILEY-VCH Verlag 2014
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3943607/
https://ncbi.nlm.nih.gov/pubmed/24688889
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201300044
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