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Total Syntheses of (−)-Pyrimidoblamic Acid and P-3A

[Image: see text] Total syntheses of (−)-pyrimidoblamic acid and P-3A are disclosed. Central to the convergent approach is a powerful inverse electron demand Diels–Alder reaction between substituted electron-deficient 1,2,3-triazines and a highly functionalized and chiral primary amidine, which form...

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Main Authors: Duerfeldt, Adam S., Boger, Dale L.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3940392/
https://ncbi.nlm.nih.gov/pubmed/24410439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja412298c
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