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Divergent Total Syntheses of (−)-Pseudocopsinine and (−)-Minovincinine
Herein the first total syntheses of (−)-pseudocopsinine (1) and (−)-minovincine (3) from a common intermediate 8 are detailed, enlisting late-stage, hydrogen atom transfer (HAT)-mediated free radical bond formations (C20–C2 and C20–OH, respectively) that are unique to their core or structure. The ap...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7718306/ https://ncbi.nlm.nih.gov/pubmed/33205969 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02493 |
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