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Convergent Diversity-Oriented Side-Chain Macrocyclization Scan for Unprotected Polypeptides

Here we describe a general synthetic platform for side-chain macrocyclization of an unprotected peptide library based on the S(N)Ar reaction between cysteine thiolates and a new generation of highly reactive perfluoroaromatic small molecule linkers. This strategy enabled us to simultaneously “scan”...

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Autors principals: Zou, Yekui, Spokoyny, Alexander M., Zhang, Chi, Simon, Mark D., Yu, Hongtao, Lin, Yu-Shan, Pentelute, Bradley L.
Format: Artigo
Idioma:Inglês
Publicat: 2014
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3935340/
https://ncbi.nlm.nih.gov/pubmed/24310320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3ob42168f
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