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Gold and BINOL-Phosphoric Acid Catalyzed Enantioselective Hydroamination/N-Sulfonyliminium Cyclization Cascade

[Image: see text] A highly enantioselective hydroamination/N-sulfonyliminium cyclization cascade is reported using a combination of gold(I) and chiral phosphoric acid catalysts. An initial 5-exo-dig hydroamination and a subsequent phosphoric acid catalyzed cyclization process provide access to compl...

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Bibliografiske detaljer
Main Authors: Gregory, Alex W., Jakubec, Pavol, Turner, Paul, Dixon, Darren J.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2013
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3931332/
https://ncbi.nlm.nih.gov/pubmed/23985045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401784h
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