טוען...
Overcoming Product Inhibition in Catalysis of the Intramolecular Schmidt Reaction
A method for carrying out the intramolecular Schmidt reaction of alkyl azides and ketones using a substoichiometric amount of catalyst is reported. Following extensive screening, the use of the strong hydrogen bond donating solvent hexafluoro-2-propanol was found to be consistent with low catalyst l...
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| Main Authors: | , , , , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2013
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3921892/ https://ncbi.nlm.nih.gov/pubmed/23687993 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402848c |
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