Preparation and characterization of pentaammineruthenium-(histidine-83)azurin: thermodynamics of intramolecular electron transfer from ruthenium to copper.

The reaction between a5RuH2O2+ (a is NH3) and Pseudomonas aeruginosa azurin at pH 7, followed by oxidation, yields a5Ru(His-83)3+-azurin(Cu2+) as the major product. Spectroscopic measurements (UV-visible, CD, EPR, and resonance Raman) indicate that the native structure is maintained in the modified...

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Main Authors: Margalit, R, Kostić, N M, Che, C M, Blair, D F, Chiang, H J, Pecht, I, Shelton, J B, Shelton, J R, Schroeder, W A, Gray, H B
Format: Artigo
Sprog:Inglês
Udgivet: 1984
Fag:
Research Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC391964/
https://ncbi.nlm.nih.gov/pubmed/6593716
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