Deuterium isotope effect on the intramolecular electron transfer in Pseudomonas aeruginosa azurin

Intramolecular electron transfer in azurin in water and deuterium oxide has been studied over a broad temperature range. The kinetic deuterium isotope effect, k(H)/k(D), is smaller than unity (0.7 at 298 K), primarily caused by the different activation entropies in water (−56.5 J K(−1) mol(−1)) and...

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Detalhes bibliográficos

Publicado no:	Proc Natl Acad Sci U S A
Principais autores:	Farver, Ole, Zhang, Jingdong, Chi, Qijin, Pecht, Israel, Ulstrup, Jens
Formato:	Artigo
Idioma:	Inglês
Publicado em:	National Academy of Sciences 2001
Assuntos:	Biological Sciences
Acesso em linha:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC31851/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/11287635/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.071043798
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