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Deuterium isotope effect on the intramolecular electron transfer in Pseudomonas aeruginosa azurin
Intramolecular electron transfer in azurin in water and deuterium oxide has been studied over a broad temperature range. The kinetic deuterium isotope effect, k(H)/k(D), is smaller than unity (0.7 at 298 K), primarily caused by the different activation entropies in water (−56.5 J K(−1) mol(−1)) and...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2001
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC31851/ https://ncbi.nlm.nih.gov/pubmed/11287635 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.071043798 |
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