Preparation and characterization of pentaammineruthenium-(histidine-83)azurin: thermodynamics of intramolecular electron transfer from ruthenium to copper.

The reaction between a5RuH2O2+ (a is NH3) and Pseudomonas aeruginosa azurin at pH 7, followed by oxidation, yields a5Ru(His-83)3+-azurin(Cu2+) as the major product. Spectroscopic measurements (UV-visible, CD, EPR, and resonance Raman) indicate that the native structure is maintained in the modified...

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Detalhes bibliográficos

Publicado no:	Proc Natl Acad Sci U S A
Principais autores:	Margalit, R, Kostić, N M, Che, C M, Blair, D F, Chiang, H J, Pecht, I, Shelton, J B, Shelton, J R, Schroeder, W A, Gray, H B
Formato:	Artigo
Idioma:	Inglês
Publicado em:	National Academy of Sciences 1984
Assuntos:	Research Article
Acesso em linha:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC391964/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/6593716/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.81.20.6554
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