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Studies on the Biosynthesis of Chetomin: Enantiospecific Synthesis of a Putative, Late-Stage Biosynthetic Intermediate
The enantiospecific synthesis of desthiochetomin, a putative biosynthetic intermediate of the epidithiodioxopiperazine natural product chetomin, is described. A diastereoselective N-alkylation was employed to form the key C3-N1’ bond of the heterodimeric indoline core, followed by peptide coupling a...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3908826/ https://ncbi.nlm.nih.gov/pubmed/24489414 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2012.10.075 |
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