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Gold(I) Carbenes by Retro-Buchner Reaction: Generation and Fate

[Image: see text] The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) car...

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Auteurs principaux: Wang, Yahui, McGonigal, Paul R., Herlé, Bart, Besora, Maria, Echavarren, Antonio M.
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2013
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3898715/
https://ncbi.nlm.nih.gov/pubmed/24358986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411626v
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