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Observation time scale, free-energy landscapes, and molecular symmetry

When structures that interconvert on a given time scale are lumped together, the corresponding free-energy surface becomes a function of the observation time. This view is equivalent to grouping structures that are connected by free-energy barriers below a certain threshold. We illustrate this time...

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Hlavní autoři: Wales, David J., Salamon, Peter
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3896148/
https://ncbi.nlm.nih.gov/pubmed/24374625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1319599111
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