Structural Analysis of the Mn(IV)/Fe(III) Cofactor of Chlamydia trachomatis Ribonucleotide Reductase by Extended X-ray Absorption Fine Structure Spectroscopy and Density Functional Theory Calculations

The class Ic ribonucleotide reductase from Chlamydia trachomatis (Ct) uses a stable Mn(IV)/Fe(III) cofactor to initiate nucleotide reduction by a free-radical mechanism. Extended X-ray absorption fine structure (EXAFS) spectroscopy and density functional theory (DFT) calculations are used to postula...

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Main Authors: Younker, Jarod M., Krest, Courtney M., Jiang, Wei, Krebs, Carsten, Bollinger, J. Martin, Green, Michael T.
Formato: Artigo
Idioma:Inglês
Publicado: 2008
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3890746/
https://ncbi.nlm.nih.gov/pubmed/18937466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja804365e
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