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Function of the diiron cluster of Escherichia coli class Ia ribonucleotide reductase in proton-coupled electron transfer
The class Ia ribonucleotide reductase (RNR) from Escherichia coli (Ec) employs a free-radical mechanism, which involves bidirectional translocation of a radical equivalent or “hole” over a distance of ∼35 Å from the stable diferric/tyrosyl-radical (Y(122)•) cofactor in the β subunit to cysteine 439...
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| Autores principales: | , , , , , , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869997/ https://ncbi.nlm.nih.gov/pubmed/23676140 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401342s |
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