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Equilibration of tyrosyl radicals (Y(356)•, Y(731)•, Y(730)•) in the radical propagation pathway of the E. coli class Ia ribonucleotide reductase
Escherichia coli ribonucleotide reductase is an α2β2 complex that catalyzes the conversion of nucleotides to deoxynucleotides using a diferric-tyrosyl radical (Y(122)•) cofactor in β2 to initiate catalysis in α2. Each turnover requires reversible long-range proton-coupled electron transfer (PCET) ov...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3236566/ https://ncbi.nlm.nih.gov/pubmed/21967342 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207455k |
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