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Total synthesis of the endogenous inflammation resolving lipid resolvin D2 using a common lynchpin

The total synthesis of the endogenous inflammation resolving eicosanoid resolvin D2 (1) is described. The key steps involved a Wittig reaction between aldehyde 5 and the ylide derived from phosphonium salt 6 to give enyne 17 and condensation of the same ylide with aldehyde 7 to afford enyne 11. Desi...

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Detalhes bibliográficos
Main Authors: Li, John, Leong, May May, Stewart, Alastair, Rizzacasa, Mark A
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869264/
https://ncbi.nlm.nih.gov/pubmed/24367439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.310
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