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Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1,4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes
[Image: see text] CHIRAL BICYCLIC: Bicyclo[5.3.0]decatrienes were prepared enantioselectively for the first time from readily available chiral 3-acyloxy-1,4-enynes (ACEs). The chirality of the allylic/propargylic esters in ACEs could be transferred with high efficiency to the bicyclic products in mo...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3867534/ https://ncbi.nlm.nih.gov/pubmed/24150975 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201306919 |
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