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Lewis Base Activation of Lewis Acids – Group 13. In Situ Generation and Reaction of Borenium Ions

A variety of Lewis bases were combined with 9-BBN-NTf(2) to establish the requirements for the generation of borenium cations. Five different types of behavior were found, but the most interesting was the combination of Et(3)N, DABCO, 2,6-lutidine, or Ph(3)P=S which formed borenium ions exclusively...

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Autors principals: Denmark, Scott E., Ueki, Yusuke
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3860277/
https://ncbi.nlm.nih.gov/pubmed/24347789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400582k
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