Highly Enantioselective Dearomatizing Formal [3+3]-Cycloaddition Reactions of N-Acyliminopyridinium Ylides with Electrophilic Enolcarbene Intermediates

[Image: see text] A effective dearomatizing formal [3+3]-cycloaddition reaction triggered by Rh(II)-catalyzed dinitrogen extrusion of enoldiazoacetates followed by vinylogous addition of metal enolcarbenes to N-acyliminopyridinium ylides that produces highly substituted 1,2,3,6-tetrahydropyridazines...

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Main Authors: Xu, Xinfang, Zavalij, Peter Y., Doyle, Michael P.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3858852/
https://ncbi.nlm.nih.gov/pubmed/24123489
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201305539
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