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Highly Enantioselective Dearomatizing Formal [3+3]-Cycloaddition Reactions of N-Acyliminopyridinium Ylides with Electrophilic Enolcarbene Intermediates
[Image: see text] A effective dearomatizing formal [3+3]-cycloaddition reaction triggered by Rh(II)-catalyzed dinitrogen extrusion of enoldiazoacetates followed by vinylogous addition of metal enolcarbenes to N-acyliminopyridinium ylides that produces highly substituted 1,2,3,6-tetrahydropyridazines...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3858852/ https://ncbi.nlm.nih.gov/pubmed/24123489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201305539 |
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