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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

The procedures described in this article involve the synthesis and isolation of hypervalent iodonium alkynyl triflates (HIATs) and their subsequent reactions with azides to form cyanocarbene intermediates. The synthesis of hypervalent iodonium alkynyl triflates can be facile, but difficulties stem f...

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Detalhes bibliográficos
Main Authors: Hyatt, I. F. Dempsey, Nasrallah, Daniel J., Croatt, Mitchell P.
Formato: Artigo
Idioma:Inglês
Publicado em: MyJove Corporation 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3857988/
https://ncbi.nlm.nih.gov/pubmed/24056681
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3791/50886
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