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Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis

Difluoromethanesulfonyl hypervalent iodonium ylides 2 were developed as electrophilic difluoromethylthiolation reagents for a wide range of nucleophiles. Enamines, indoles, β-keto esters, silyl enol ethers and pyrroles were effectively reacted with 2 affording desired difluoromethylthio (SCF(2)H)-su...

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Detalhes bibliográficos
Publicado no:R Soc Open Sci
Main Authors: Arimori, Sadayuki, Matsubara, Okiya, Takada, Masahiro, Shiro, Motoo, Shibata, Norio
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4892452/
https://ncbi.nlm.nih.gov/pubmed/27293790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsos.160102
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