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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

The procedures described in this article involve the synthesis and isolation of hypervalent iodonium alkynyl triflates (HIATs) and their subsequent reactions with azides to form cyanocarbene intermediates. The synthesis of hypervalent iodonium alkynyl triflates can be facile, but difficulties stem f...

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Bibliografiske detaljer
Main Authors: Hyatt, I. F. Dempsey, Nasrallah, Daniel J., Croatt, Mitchell P.
Format: Artigo
Sprog:Inglês
Udgivet: MyJove Corporation 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3857988/
https://ncbi.nlm.nih.gov/pubmed/24056681
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3791/50886
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