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Spectral studies of a Cr(PNP)-MAO system for selective ethylene trimerization catalysis: searching for the active species
Variable temperature spectroscopic, kinetic, and chemical studies were performed on a soluble Cr(III)Cl(3)(PNP) (PNP = bis(diarylphosphino)alkylamine) ethylene trimerization precatalyst to map out its methylaluminoxane (MAO) activation sequence. These studies indicate that treatment of Cr(III)Cl(3)(...
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Main Authors: | , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2013
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3855459/ https://ncbi.nlm.nih.gov/pubmed/24327931 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400778a |
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