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Spectral studies of a Cr(PNP)-MAO system for selective ethylene trimerization catalysis: searching for the active species

Variable temperature spectroscopic, kinetic, and chemical studies were performed on a soluble Cr(III)Cl(3)(PNP) (PNP = bis(diarylphosphino)alkylamine) ethylene trimerization precatalyst to map out its methylaluminoxane (MAO) activation sequence. These studies indicate that treatment of Cr(III)Cl(3)(...

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Detalhes bibliográficos
Main Authors: Do, Loi H., Labinger, Jay A., Bercaw, John E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3855459/
https://ncbi.nlm.nih.gov/pubmed/24327931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400778a
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