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Efficient and Selective Catalysis for Hydrogenation and Hydrosilation of Alkenes and Alkynes with PNP Complexes of Scandium and Yttrium†

Scandium and yttrium congeneric complexes, supported by a monoanionic PNP ligand, were studied as catalysts for alkene hydrogenation and hydrosilation, and alkyne semihydrogenation and semihydrosilation. The yttrium congener was found to be much more active in all cases, but this greater activity is...

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Publicado en:Chem Commun (Camb)
Autores principales: Levine, Daniel S., Tilley, T. Don, Andersen, Richard A.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2017
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5709034/
https://ncbi.nlm.nih.gov/pubmed/29043320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc06417a
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