Are multiple oxygen species selective in ethylene epoxidation on silver?

The nature of the oxygen species active in ethylene epoxidation is a long-standing question. While the structure of the oxygen species that participates in total oxidation (nucleophilic oxygen) is known the atomic structure of the selective species (electrophilic oxygen) is still debated. Here, we u...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Carbonio, Emilia A., Rocha, Tulio C. R., Klyushin, Alexander Yu., Píš, Igor, Magnano, Elena, Nappini, Silvia, Piccinin, Simone, Knop-Gericke, Axel, Schlögl, Robert, Jones, Travis E.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2017
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5874983/
https://ncbi.nlm.nih.gov/pubmed/29629166
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04728b
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